Title data
Simon, Peter ; Mang, Stefan ; Hasenhindl, A. ; Gronski, W. ; Greiner, Andreas:
Poly(p-xylylene) and its derivatives by chemical vapor deposition: Synthesis, mechanism, and structure.
In: Macromolecules.
Vol. 31
(December 1998)
Issue 25
.
- pp. 8775-8780.
ISSN 0024-9297
DOI: https://doi.org/10.1021/ma9808070
Abstract in another language
Poly(p-xylylene) (PPX) and its derivatives were prepared by vapor-phase pyrolysis and subsequent chemical vapor deposition (CVD) of the pyrolysis products. Readily available esters of alpha,alpha'-dihydroxy-p-xylylenes were utilized as starting materials. Mechanistical studies prove that 1,4-quinodimethane is formed by pyrolysis of diesters. The PPXs obtained compare well to PPXs obtained by the classical route using 2.2]paracyclophanes. C-13 CP-MAS NMR spectroscopy indicates that the arrangement of substituents along the polymer main chain is controlled by the size of substituents.
Further data
Item Type: | Article in a journal |
---|---|
Refereed: | Yes |
Institutions of the University: | Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II |
Result of work at the UBT: | No |
DDC Subjects: | 500 Science > 540 Chemistry |
Date Deposited: | 15 Apr 2015 13:30 |
Last Modified: | 12 Apr 2018 08:27 |
URI: | https://eref.uni-bayreuth.de/id/eprint/10238 |