Poly(p-xylylene) and its derivatives by chemical vapor deposition: Synthesis, mechanism, and structure

Title data

Simon, Peter ; Mang, Stefan ; Hasenhindl, A. ; Gronski, W. ; Greiner, Andreas:
Poly(p-xylylene) and its derivatives by chemical vapor deposition: Synthesis, mechanism, and structure.
In: Macromolecules. Vol. 31 (December 1998) Issue 25 . - pp. 8775-8780.
ISSN 0024-9297
DOI: https://doi.org/10.1021/ma9808070

Official URL:

Abstract in another language

Poly(p-xylylene) (PPX) and its derivatives were prepared by vapor-phase pyrolysis and subsequent chemical vapor deposition (CVD) of the pyrolysis products. Readily available esters of alpha,alpha'-dihydroxy-p-xylylenes were utilized as starting materials. Mechanistical studies prove that 1,4-quinodimethane is formed by pyrolysis of diesters. The PPXs obtained compare well to PPXs obtained by the classical route using 2.2]paracyclophanes. C-13 CP-MAS NMR spectroscopy indicates that the arrangement of substituents along the polymer main chain is controlled by the size of substituents.

Further data

Item Type:	Article in a journal
Refereed:	Yes
Institutions of the University:	Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner Faculties Faculties > Faculty of Biology, Chemistry and Earth Sciences Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT:	No
DDC Subjects:	500 Science > 540 Chemistry
Date Deposited:	15 Apr 2015 13:30
Last Modified:	12 Apr 2018 08:27
URI:	https://eref.uni-bayreuth.de/id/eprint/10238