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Simple poly(p-xylylene)s as precursor polymers for poly(p-phenylenevinylene)s and segmented poly(p-phenylenevinylene)s: synthesis, polymer analogous reactions, and thermal and optical properties

Title data

Schäfer, Oliver ; Mang, Stefan ; Arici, Elif ; Lüssem, Georg ; Unterlechner, Christoph ; Wendorff, Joachim H. ; Greiner, Andreas:
Simple poly(p-xylylene)s as precursor polymers for poly(p-phenylenevinylene)s and segmented poly(p-phenylenevinylene)s: synthesis, polymer analogous reactions, and thermal and optical properties.
In: Macromolecular Chemistry and Physics. Vol. 199 (May 1998) Issue 5 . - pp. 807-813.
ISSN 1521-3935
DOI: https://doi.org/10.1002/(SICI)1521-3935(19980501)199:5<807::AID-MACP807>3.0.CO;2-W

Official URL: Volltext

Abstract in another language

The preparation of a high molecular weight soluble derivative of poly(p-xylylene) by vapor phase pyrolysis followed by chemical vapor deposition (CVD) and its dehydrogenation with 1,2-dichloro-3,4-dicyanoquinone (DDQ) to yield the corresponding derivative of poly(phenylenevinylene) is reported. Derivatives of poly(phenylenevinylene)s with nonconjugated segments were prepared by partial dehydrogenation with substoichiometric amounts of DDQ. The thermal and optical properties of segmented and nonsegmented poly(p-phenylenevinylene)s are compared as well as their electroluminescence properties with particular focus on the quantum yields.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: CHEMICAL-VAPOR-DEPOSITION; FILM; POLY(1,4-PHENYLENEVINYLENE)
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 16 Apr 2015 09:39
Last Modified: 16 Apr 2015 09:39
URI: https://eref.uni-bayreuth.de/id/eprint/10245