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Synthesis and properties of a soluble, rigid poly(p-xylylene) with high molecular weight

Title data

Schäfer, Oliver ; Greiner, Andreas ; Antonietti, Markus ; Zisenis, M.:
Synthesis and properties of a soluble, rigid poly(p-xylylene) with high molecular weight.
In: Acta Polymerica. Vol. 47 (September 1996) Issue 9 . - pp. 386-390.
ISSN 1521-4044

Abstract in another language

The synthesis of a linear, soluble poly(p-xylylene) with high molecular weight, the phenethyl-substituted PPX (PEPPX), via a base-induced polyreaction is presented. The resulting polymers are characterized by GPC and static and dynamic light scattering. The light scattering data clearly demonstrate that PEPPX in THF is a very stiff, shape-persistent polymer with a persistence length of the order of at least 18 nm. This is rather unexpected since PPX contains two main chain cc-bonds in each monomer unit, which allow free rotation.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: ISI:A1996VJ35800003
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 16 Apr 2015 11:47
Last Modified: 16 Apr 2015 11:47
URI: https://eref.uni-bayreuth.de/id/eprint/10288