Titlebar

Export bibliographic data
Literature by the same author
plus on the publication server
plus at Google Scholar

 

Crystallization kinetics of PEO and PE in different triblock terpolymers : Effect of microdomain geometry and confinement

Title data

Boschetti-de-Fierro, Adriana ; Lorenzo, Arnaldo T. ; Müller, Alejandro J. ; Schmalz, Holger ; Abetz, Volker:
Crystallization kinetics of PEO and PE in different triblock terpolymers : Effect of microdomain geometry and confinement.
In: Macromolecular Chemistry and Physics. Vol. 209 (5 March 2008) Issue 5 . - pp. 476-487.
ISSN 1521-3935
DOI: https://doi.org/10.1002/macp.200700434

Official URL: Volltext

Abstract in another language

The isothermal crystallization kinetics of PEO and PE blocks within various triblock terpolymers were studied by DSC. The effect of the geometry of the microdomains was analyzed by studying different compositions of PE-b-PS-b-PEO triblock terpolymers. The crystallization rate decreased for decreasing block content for both crystallizable blocks. The effect of the microdomain geometry, confinement or chain tethering on the crystallization of PEO was extensively studied by comparing pairs of triblock terpolymers with differences either in the nature (crystalline, glassy, amorphous) or in the location of the other blocks in the terpolymer.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: ISI:000254181700003
Keywords: block copolymers; crystallization; differential scanning calorimetry (DSC); morphology
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 15 Apr 2015 08:34
Last Modified: 15 Apr 2015 08:34
URI: https://eref.uni-bayreuth.de/id/eprint/10385