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A New Class of Ultra-Efficient Supramolecular Nucleating Agents for Isotactic Polypropylene

Title data

Abraham, Frank ; Kress, Roman ; Smith, Paul ; Schmidt, Hans-Werner:
A New Class of Ultra-Efficient Supramolecular Nucleating Agents for Isotactic Polypropylene.
In: Macromolecular Chemistry and Physics. Vol. 214 (2013) Issue 1 . - pp. 17-24.
ISSN 1521-3935
DOI: https://doi.org/10.1002/macp.201200487

Project information

Project financing: Deutsche Forschungsgemeinschaft

Abstract in another language

We present a family of 2,4,6-trimethyl-1,3,5-benzenetrisamides for ultra-efficient nucleation of isotactic polypropylene (i-PP). On the basis of a new symmetrically substituted core, in a series of compounds, the chemical structure of peripheral substituents was systematically varied, introducing branched aliphatic, aromatic, and cycloaliphatic moieties. Some of these compounds were found to promote nucleation of the a-phase in i-PP at concentrations as lowas 0.00003 wt%only,while concomitantly featuring outstanding thermal properties.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I > Chair Macromolecular Chemistry I - Univ.-Prof. Dr. Hans-Werner Schmidt
Profile Fields
Profile Fields > Advanced Fields
Profile Fields > Advanced Fields > Polymer and Colloid Science
Profile Fields > Advanced Fields > Advanced Materials
Research Institutions
Research Institutions > Research Centres
Research Institutions > Research Centres > Bayreuth Institute of Macromolecular Research - BIMF
Research Institutions > Research Centres > Bayreuth Center for Colloids and Interfaces - BZKG
Research Institutions > Collaborative Research Centers, Research Unit
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP B 4
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 06 Jul 2015 07:28
Last Modified: 06 Jul 2015 07:28
URI: https://eref.uni-bayreuth.de/id/eprint/1144