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Straightforward Synthesis of all Stenusine and Norstenusine Stereoisomers

Title data

Müller, Tobias ; Dettner, Konrad ; Seifert, Karlheinz:
Straightforward Synthesis of all Stenusine and Norstenusine Stereoisomers.
In: European Journal of Organic Chemistry. Vol. 30 (2011) . - pp. 6032-6038.
ISSN 1099-0690
DOI: https://doi.org/10.1002/ejoc.201100612

Abstract in another language

All the stereoisomers of stenusine (1) and norstenusine (21) have been efficiently synthesized by the asymmetric hydrogenation of pyridines. The (2R,3S)- and (2R,3R)-isomers of 1, that are difficult to prepare, have been synthesized for the first time using a chemoenzymatic approach in eight steps with an 8 % total yield. All the target compounds were obtained in good stereochemical purity by using very simple and inexpensive reagents and auxiliaries.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: BAYCEER97490
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology > Chair Animal Ecology II - Evolutionary Animal Ecology
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology > Former Professors > Chair Animal Ecology II - Univ.-Prof. Dr. Konrad Dettner
Research Institutions > Research Centres > Bayreuth Center of Ecology and Environmental Research- BayCEER
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology
Research Institutions
Research Institutions > Research Centres
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Biology > Former Professors
Result of work at the UBT: Yes
DDC Subjects: 500 Science
Date Deposited: 29 Apr 2015 15:42
Last Modified: 29 Apr 2015 15:42
URI: https://eref.uni-bayreuth.de/id/eprint/11700