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Preparation and characterization of new trifluoromethylmercaptoaminoboranes

Title data

Haas, Alois ; Willert-Porada, Monika:
Preparation and characterization of new trifluoromethylmercaptoaminoboranes.
In: Journal of Fluorine Chemistry. Vol. 23 (November 1983) Issue 5 . - p. 427.
ISSN 1873-3328
DOI: https://doi.org/10.1016/S0022-1139(00)85502-5

Abstract in another language

Reactions of BX3 (X = Cl, Br, SCF3 ) with substituted trifluoromethylmercaptoamines such as [(CF3S)2N]2Hg, Me3SnN(SCF3)2, Me3SiN(SCF3)2, Me3SiN(SCF3)H and (Me3Si)2NSCF3 have been investigated. Using [(CF3S)2N]2Hg and Me3SnN(SCF3)2 in metathetical reactions with BX3 the new aminoboranes XnB[N(SCF3)2]3−n (n = O, 1) can be synthetized. The best yields are obtained from BX3 and Hg[N(SCF3)2]2. Trimethylsilyl-trifluoromethylmercaptoamine, Me3 SiNSCF3 (H), reacts with BCl3 to form (CF3 SNH)nBCl3−n.
The reactivity of SiN, SN, HgN, SnN and HN-bonds towards BX3 will be discussed. Spectroscopical data (19F−,11B−, 14/15N−, 29Si−, 119Sn−, 1H.NMR, MS, IR, Ra) for the new compounds B[N(SCF3)2]3 , ClB[N(SCF3)2]2, BrB[N(SCF3)2]2, HN(SCF3)SiMe3 and Me3SnN(SCF3)2 will be presented.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Ehemalige Professoren > Chair Materials Processing - Univ.-Prof. Dr. Monika Willert-Porada
Faculties
Faculties > Faculty of Engineering Science > Ehemalige Professoren
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 500 Natural sciences
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 14 Aug 2017 07:25
Last Modified: 14 Aug 2017 07:34
URI: https://eref.uni-bayreuth.de/id/eprint/11796