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Reactions of Trifluormethylthioamines with Reducing Agents

Title data

Haas, Alois ; Willert-Porada, Monika:
Reactions of Trifluormethylthioamines with Reducing Agents.
In: Journal of Fluorine Chemistry. Vol. 29 (August 1985) Issue 1-2 . - p. 158.
ISSN 1873-3328
DOI: https://doi.org/10.1016/S0022-1139(00)83394-1

Abstract in another language

Reactions of trifluoromethylthioamines (CF3S)3-nNHn with NaH (n = 0, 1, 2), NaBH4, NaNH2 (n = 1, 2) and NaOR (R = CH3, C2H5; n = 1) occur with differing sites of attack on the amin. Results of the NaH-reactions suggest that nucleophilic attack takes place at the hydrogen, nitrogen or sulphur atoms. With NaBH4 the amines CF3SNH2 and (CF3S)2NH behave as Lewis acids. In the presence of J2 as trapping- reagent for the hydride-ion the adduct (CF3S)2NH·BH3 could be isolated. Degradation of the amine occurs upon reaction with NaOR; however with NaNH2 an exchange reaction is observed. 15/14N-NMR-data for the trifluoromethylthioamines and several derivatives (silyl-, stannyl- and boric-) are presented.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Ehemalige Professoren > Chair Materials Processing - Univ.-Prof. Dr. Monika Willert-Porada
Faculties
Faculties > Faculty of Engineering Science > Ehemalige Professoren
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 500 Natural sciences
600 Technology, medicine, applied sciences > 620 Engineering
Date Deposited: 14 Aug 2017 07:35
Last Modified: 14 Aug 2017 07:35
URI: https://eref.uni-bayreuth.de/id/eprint/11798