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Ordered Heterostructures of Two Strictly Alternating Types of Nanoreactors

Title data

Stöter, Matthias ; Biersack, Bernhard ; Reimer, Nele ; Herling, Markus M. ; Stock, Norbert ; Schobert, Rainer ; Breu, Josef:
Ordered Heterostructures of Two Strictly Alternating Types of Nanoreactors.
In: Chemistry of Materials. Vol. 26 (2 September 2014) Issue 18 . - pp. 5412-5419.
ISSN 1520-5002
DOI: https://doi.org/10.1021/cm502816a

Abstract in another language

One-dimensional crystalline heterostructures of two types of nanoreactors strictly alternating along the stacking direction are obtained by partial ion exchange into a synthetic clay mineral distinguished by an outstandingly homogeneous charge density. The driving force for the formation of these high interface architectures is proven to be founded in densely packed cationic molecules in the interlayer with a charge density deviating from the charge density of the host clay mineral. The established mechanism renders the approach generally applicable and will allow for synthesis of ordered heterostructures of any desired combination of functional molecules that moreover are separated by exactly 1 nm thick silicate walls. The ordered heterostructures were furthermore shown to represent the thermodynamic equilibrium suggesting the mechanism of formation to be robust.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I > Chair Organic Chemistry I - Univ.-Prof. Dr. Rainer Schobert
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP A 6
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Organic Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Research Institutions
Research Institutions > Collaborative Research Centers, Research Unit
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 26 Mar 2018 09:00
Last Modified: 26 Mar 2018 09:00
URI: https://eref.uni-bayreuth.de/id/eprint/12675