Synthesis of arylsubstituted monomers for high-performance polymers

Titelangaben

Land, Horst-Tore ; Hatke, Wilfried ; Greiner, Andreas ; Schmidt, Hans-Werner ; Heitz, Walter:
Synthesis of arylsubstituted monomers for high-performance polymers.
In: Die Makromolekulare Chemie. Bd. 191 (1990) Heft 9 . - S. 2005-2016.
ISSN 0025-116X
DOI: https://doi.org/10.1002/macp.1990.021910903

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Abstract

The arylation of monomers for high-performance polymers is described. The reaction of dibenzoyl peroxide with various 1,4-disubstituted benzene derivatives results in phenylation. Minimization of side reactions is discussed. The Ni-promoted reaction of Grignard compounds with iodoarenes was used to introduce the phenyl, biphenyl, and naphthyl substituent.