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Synthesis of monomers and polymers by the Heck reaction

Title data

Heitz, Walter ; Brügging, Wilhelm ; Freund, Lothar ; Gailberger, Michael ; Greiner, Andreas ; Jung, Holger ; Kampschulte, Uwe ; Nießner, Norbert ; Osan, Frank ; Schmidt, Hans-Werner ; Wicker, Michael:
Synthesis of monomers and polymers by the Heck reaction.
In: Die Makromolekulare Chemie. Vol. 189 (1988) . - pp. 119-127.
ISSN 0025-116X
DOI: https://doi.org/10.1002/macp.1988.021890112

Official URL: Volltext

Abstract in another language

The Heck reaction allows the synthesis of monomers in a one-step reaction. Catalyzed by Pd, bromoarenes are reacted with ethylene to form substituted styrenes and symmetrical stilbenes. Unsymmetrical stilbenes are obtained from substituted bromoarenes and styrenes. Substituted hydroquinones and terephthalic acids are also available in high yields. Poly(1,4-phenylenevinylene) is obtained starting from 4-bromostyrene.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry I > Chair Macromolecular Chemistry I - Univ.-Prof. Dr. Hans-Werner Schmidt
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Profile Fields > Advanced Fields > Polymer and Colloid Science
Profile Fields
Profile Fields > Advanced Fields
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 16 Apr 2015 10:51
Last Modified: 09 Apr 2019 08:45
URI: https://eref.uni-bayreuth.de/id/eprint/1662