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Solid State Structures of Cyclopentadienyllithium, -sodium, and -potassium : determination by High-Resolution Powder Diffraction

Title data

Dinnebier, Robert E. ; Behrens, Ulrich ; Olbrich, Falk:
Solid State Structures of Cyclopentadienyllithium, -sodium, and -potassium : determination by High-Resolution Powder Diffraction.
In: Organometallics. Vol. 16 (1997) Issue 17 . - pp. 3855-3858.
ISSN 1520-6041
DOI: https://doi.org/10.1021/om9700122

Abstract in another language

The structures of MCp (M = Li, Na, K; Cp = cyclopentadienyl), some of the most important precursors in synthetic organometallic chemistry, have been investigated. All three compounds form polymeric “multidecker structures”. In LiCp and NaCp the metal atoms form a “string of pearls” whereas the potassium atoms in KCp are arranged in a zigzag chain that interacts with neighboring chains.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography
Faculties
Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
Date Deposited: 14 Jun 2016 12:31
Last Modified: 14 Jun 2016 12:31
URI: https://eref.uni-bayreuth.de/id/eprint/32676