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Ihli, Johannes ; Clark, Jesse N. ; Côté, Alexander S. ; Kim, Yi-Yeoun ; Schenk, Anna ; Kulak, Alexander N. ; Comyn, Timothy P. ; Chammas, Oliver ; Harder, Ross J. ; Duffy, Dorothy M. ; Robinson, Ian K. ; Meldrum, Fiona C.:
Strain-relief by single dislocation loops in calcite crystals grown on self-assembled monolayers.
In: Nature Communications.
Bd. 7
(2016)
.
- No. 11878.
ISSN 2041-1723
DOI: https://doi.org/10.1038/ncomms11878
Abstract
Most of our knowledge of dislocation-mediated stress relaxation during epitaxial crystal growth comes from the study of inorganic heterostructures. Here we use Bragg coherent diffraction imaging to investigate a contrasting system, the epitaxial growth of calcite (CaCO3) crystals on organic self-assembled monolayers, where these are widely used as a model for biomineralization processes. The calcite crystals are imaged to simultaneously visualize the crystal morphology and internal strain fields. Our data reveal that each crystal possesses a single dislocation loop that occupies a common position in every crystal. The loops exhibit entirely different geometries to misfit dislocations generated in conventional epitaxial thin films and are suggested to form in response to the stress field, arising from interfacial defects and the nanoscale roughness of the substrate. This work provides unique insight into how self-assembled monolayers control the growth of inorganic crystals and demonstrates important differences as compared with inorganic substrates.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Juniorprofessur Kolloidale Systeme > Juniorprofessur Kolloidale Systeme - Juniorprof. Dr. Anna Schenk Fakultäten Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Juniorprofessur Kolloidale Systeme |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 21 Feb 2017 12:59 |
| Letzte Änderung: | 15 Feb 2023 10:31 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/36169 |