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Reversibly Actuating Solid Janus Polymeric Fibers

Titelangaben

Ionov, Leonid ; Stoychev, Georgi ; Jehnichen, Dieter ; Sommer, Jens Uwe:
Reversibly Actuating Solid Janus Polymeric Fibers.
In: ACS Applied Materials & Interfaces. Bd. 9 (8 Februar 2017) Heft 5 . - S. 4873-4881.
ISSN 1944-8252
DOI: 10.1021/acsami.6b13084

Abstract

It is commonly assumed that the substantial element of reversibly actuating soft polymeric materials is chemical cross-linking, which is needed to provide elasticity required for the reversible actuation. On the example of melt spun and three-dimensional printed Janus fibers, we demonstrate here for the first time that cross-linking is not an obligatory prerequisite for reversible actuation of solid entangled polymers, since the entanglement network itself can build elasticity during crystallization. Indeed, we show that not-cross-linked polymers, which typically demonstrate plastic deformation in melt, possess enough elastic behavior to actuate reversibly. The Janus polymeric structure bends because of contraction of the polymer and due to entanglements and formation of nanocrystallites upon cooling. Actuation upon melting is simply due to relaxation of the stressed nonfusible component. This approach opens perspectives for design of solid active materials and actuator for robotics, biotechnology, and smart textile applications. The great advantage of our principle is that it allows design of non-cross-linked self-moving materials, which are able to actuate in both water and air, which are not cross-linked. We demonstrate application of actuating fibers for design of walkers, structures with switchable length, width, and thickness, which can be used for smart textile applications.It is commonly assumed that the substantial element of reversibly actuating soft polymeric materials is chemical cross-linking, which is needed to provide elasticity required for the reversible actuation. On the example of melt spun and three-dimensional printed Janus fibers, we demonstrate here for the first time that cross-linking is not an obligatory prerequisite for reversible actuation of solid entangled polymers, since the entanglement network itself can build elasticity during crystallization. Indeed, we show that not-cross-linked polymers, which typically demonstrate plastic deformation in melt, possess enough elastic behavior to actuate reversibly. The Janus polymeric structure bends because of contraction of the polymer and due to entanglements and formation of nanocrystallites upon cooling. Actuation upon melting is simply due to relaxation of the stressed nonfusible component. This approach opens perspectives for design of solid active materials and actuator for robotics, biotechnology, and smart textile applications. The great advantage of our principle is that it allows design of non-cross-linked self-moving materials, which are able to actuate in both water and air, which are not cross-linked. We demonstrate application of actuating fibers for design of walkers, structures with switchable length, width, and thickness, which can be used for smart textile applications.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation > Professur Biofabrikation - Univ.-Prof. Dr. Leonid Ionov
Fakultäten
Fakultäten > Fakultät für Ingenieurwissenschaften
Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 21 Jun 2017 09:52
Letzte Änderung: 21 Jun 2017 09:52
URI: https://eref.uni-bayreuth.de/id/eprint/37705