Titlebar

Export bibliographic data
Literature by the same author
plus on the publication server
plus at Google Scholar

 

Solvent Influence on the Magnetic Properties of Iron(II) Spin-Crossover Coordination Compounds with 4,4'-Dipyridylethyne as Linker

Title data

Dankhoff, Katja ; Lochenie, Charles ; Puchtler, Florian ; Weber, Birgit:
Solvent Influence on the Magnetic Properties of Iron(II) Spin-Crossover Coordination Compounds with 4,4'-Dipyridylethyne as Linker.
In: European Journal of Inorganic Chemistry. Vol. 2016 (2016) Issue 13-14 . - pp. 2136-2143.
ISSN 1099-0682
DOI: https://doi.org/10.1002/ejic.201501175

Abstract in another language

New iron(II) coordination polymers with solvent-dependent spin-crossover behaviour have been synthesised by using an N2O2 Schiff base like ligand and 4,4′-dipyridylethyne as the bridging axial ligand in different solvents. The effects of different solvents and preparation methods (temperature, concentration) on the magnetic properties have been investigated. Annealing the coordination polymers prepared by the same method but in different solvents led to the same compound exhibiting the same three-step spin crossover independent of the magnetic properties of the solvated species. The X-ray structures of the axial ligand, an iron(II) dimer and one of the iron(II) coordination polymers are discussed. Powder X-ray diffraction analysis was additionally used for further comparison of the compounds.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 11:29
Last Modified: 25 Jul 2017 11:29
URI: https://eref.uni-bayreuth.de/id/eprint/38801