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Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands : 1D coordination polymers

Title data

Lochenie, Charles ; Gebauer, Andreas ; Klimm, Ottokar ; Puchtler, Florian ; Weber, Birgit:
Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands : 1D coordination polymers.
In: New Journal of Chemistry. Vol. 40 (2016) Issue 5 . - pp. 4687-4695.
ISSN 1369-9261
DOI: https://doi.org/10.1039/C5NJ02470F

Abstract in another language

The synthesis of iron(II) coordination polymers of new Schiff base-like ligands with an extended π-system is described. In total sixteen new compounds were synthesised. The complexes were characterised by X-ray powder diffraction and magnetic measurements. Four of these complexes remain in the low-spin state and six remain in the high-spin state in the entire temperature range investigated. The remaining six complexes show a spin crossover behaviour with a cooperative spin transition (28 and 40 K wide hysteresis loops) in two cases. The influence of the extended aromatic system on cooperative interactions is discussed.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 11:45
Last Modified: 25 Jul 2017 11:45
URI: https://eref.uni-bayreuth.de/id/eprint/38803