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Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands : mononuclear complexes

Title data

Lochenie, Charles ; Heinz, Julia ; Milius, Wolfgang ; Weber, Birgit:
Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands : mononuclear complexes.
In: Dalton Transactions. Vol. 44 (2015) Issue 41 . - pp. 18065-18077.
ISSN 1477-9234
DOI: https://doi.org/10.1039/C5DT03048J

Abstract in another language

The synthesis of new Schiff base-like ligands with extended π-system and their iron complexes is described. Some of the iron(II) complexes with N-heterocycles as axial ligands show spin crossover behaviour. The influence of the extended aromatic system on cooperative interactions is investigated by single crystal X-ray structure analysis, X-ray powder diffraction, and magnetic measurements. A combination of C–H⋯π and C–H⋯O interactions is made responsible for up to 10 K wide thermal hysteresis loops.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 12:11
Last Modified: 25 Jul 2017 12:11
URI: https://eref.uni-bayreuth.de/id/eprint/38805