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Modulation of the ligand-based fluorescence of 3d metal complexes upon spin state change

Title data

Lochenie, Charles ; Wagner, Kristina G. ; Karg, Matthias ; Weber, Birgit:
Modulation of the ligand-based fluorescence of 3d metal complexes upon spin state change.
In: Journal of Materials Chemistry C. Vol. 3 (2015) Issue 30 . - pp. 7925-7935.
ISSN 2050-7534
DOI: https://doi.org/10.1039/C5TC00837A

Abstract in another language

Two new Schiff base-like ligands bearing a heteroaromatic fluorophore were synthesised and converted into the corresponding Ni(II), Cu(II) and Zn(II) square planar complexes. The Ni(II) complexes were studied with regard to a coordination change-induced spin state change upon addition of pyridine in solution. An inverse correlation between the fluorescence properties and the spin state of the metal centre was observed, and investigated with steady state fluorescence and time-resolved spectroscopy.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 12:14
Last Modified: 25 Jul 2017 12:14
URI: https://eref.uni-bayreuth.de/id/eprint/38806