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Water channels and zipper structures in Schiff base-like Cu(II) and Ni(II) mononuclear complexes

Title data

Lochenie, Charles ; Schlamp, Stephan ; Railliet, Antoine P. ; Robeyns, Koen ; Weber, Birgit ; Garcia, Yann:
Water channels and zipper structures in Schiff base-like Cu(II) and Ni(II) mononuclear complexes.
In: CrystEngComm. Vol. 16 (2014) Issue 27 . - pp. 6213-6218.
ISSN 1466-8033
DOI: https://doi.org/10.1039/C4CE00710G

Abstract in another language

The crystal structures of four Cu(II) complexes and one Ni(II) complex bearing a square planar N2O2 coordination sphere are discussed. In all cases a distorted square planar coordination sphere is observed that is independent of the metal centre and the ligand and is only influenced by the packing of the molecules in the crystal. For the less distorted copper complexes metal–aromatic interactions are observed, while no significant intermolecular interactions are found for the nickel complexes. This can be explained by the different electronic character of Cu(II) and Ni(II) and is also reflected in the differences in the solvatochromism of these complexes.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 13:36
Last Modified: 25 Jul 2017 13:36
URI: https://eref.uni-bayreuth.de/id/eprint/38812