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Amphiphilic iron(II) complexes with short alkyl chains : crystal packing and spin transition properties

Title data

Schlamp, Stephan ; Dankhoff, Katja ; Weber, Birgit:
Amphiphilic iron(II) complexes with short alkyl chains : crystal packing and spin transition properties.
In: New Journal of Chemistry. Vol. 38 (2014) Issue 5 . - pp. 1965-1972.
ISSN 1369-9261
DOI: https://doi.org/10.1039/C3NJ00991B

Abstract in another language

An amphiphilic iron(II) spin crossover complex with relatively short octyl chains was synthesised and the crystal structures of the high spin and the low spin state could be determined. In further reactions, a second modification of the hexa-coordinated complex and two different penta-coordinated complexes could be obtained and characterised by X-ray structure analysis. The examples demonstrate an influence of the alkyl chains on the stoichiometry of the final product. Different arrangements of the alkyl chains were observed in the crystal packing. Despite those differences, the spin transition of the hexa-coordinated complexes is always gradual and comparable to that observed in solution.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 25 Jul 2017 13:40
Last Modified: 25 Jul 2017 13:40
URI: https://eref.uni-bayreuth.de/id/eprint/38813