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Magnetic Ordering in Iron(II) Complexes due to a 2D Network of Hydrogen Bonds

Title data

Weber, Birgit ; Jäger, Ernst-G.:
Magnetic Ordering in Iron(II) Complexes due to a 2D Network of Hydrogen Bonds.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 635 (2009) Issue 1 . - pp. 130-133.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200800338

Abstract in another language

The magnetic properties of two octahedral iron(II) complexes with Schiff base like equatorial N2O2 coordinating ligands and methanol (MeOH) as axial ligand are reported. Both compounds [FeL1(MeOH)2] (1) and [FeL2(MeOH)2] (2) (with L1 = [3,3′]-[1,2-phenylenebis(iminomethylidyne)-bis(2,4-pentanedionato)(2-)-N,N′,O2,O2′] and L2 = [E,E]-[{diethyl 2,2′-1,2-phenylenebis(iminomethylidyne)bis(3-oxo-3-phenylpropanato)} (2-)-N,N′,O3,O3′]) show a weak spontaneous magnetization below TC = 10 K. Results from X-ray structure analysis of 1 indicate, that this is due to 2D network of hydrogen bonds as previously discussed for a similar complex.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 27 Jul 2017 12:45
Last Modified: 27 Jul 2017 12:45
URI: https://eref.uni-bayreuth.de/id/eprint/38845