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Facile Synthesis and Chain-Length Dependence of the Optical and Structural Properties of Diketopyrrolopyrrole-Based Oligomers

Titelangaben

Mukhopadhyay, Tushita ; Puttaraju, Boregowda ; Roy, Palas ; Dasgupta, Jyotishman ; Meyer, Andreas ; Rudnick, Alexander ; Tscheuschner, Steffen ; Kahle, Frank-Julian ; Köhler, Anna ; Patil, Satish:
Facile Synthesis and Chain-Length Dependence of the Optical and Structural Properties of Diketopyrrolopyrrole-Based Oligomers.
In: Chemistry : a European Journal. Bd. 23 (2017) Heft 55 . - S. 13718-13723.
ISSN 1521-3765
DOI: https://doi.org/10.1002/chem.201702131

Abstract

Here, we report the synthesis, optical properties, and solid-state packing of monodisperse oligomers of diketopyrrolopyrrole (DPP) up to five repeating units. The optical properties of DPP oligomers in solution and the solid state were investigated by a combination of steady-state and transient spectroscopy. Transient absorption spectroscopy and time-correlated single photon counting (TCSPC) measurements show that the fluorescence lifetime decreases with an increase in the oligomer size from monomer to trimer, thereby reaching saturation for pentameric DPP oligomers. The solid-state packing and crystallinity were probed by using advanced techniques, which included grazing incidence small-angle X-ray scattering (GISAXS) and X-ray diffraction (XRD) to elucidate the structure–property trend. Collectively, our chain-length dependent studies establish the fundamental correlation between the structure and property and provide a comprehensive understanding of the solid-state properties in DPP–DPP based conjugated systems.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Mathematik, Physik und Informatik > Physikalisches Institut
Fakultäten > Fakultät für Mathematik, Physik und Informatik > Physikalisches Institut > Lehrstuhl Experimentalphysik II - Optoelektronik weicher Materie > Lehrstuhl Experimentalphysik II - Optoelektronik weicher Materie - Univ.-Prof. Dr. Anna Köhler
Fakultäten
Fakultäten > Fakultät für Mathematik, Physik und Informatik
Fakultäten > Fakultät für Mathematik, Physik und Informatik > Physikalisches Institut > Lehrstuhl Experimentalphysik II - Optoelektronik weicher Materie
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 530 Physik
Eingestellt am: 13 Okt 2017 08:11
Letzte Änderung: 29 Aug 2018 06:43
URI: https://eref.uni-bayreuth.de/id/eprint/39977