Titlebar

Bibliografische Daten exportieren
Literatur vom gleichen Autor
plus auf ERef Bayreuth
plus bei Google Scholar

 

Hierarchical Porous Carbon Cathode for Lithium–Sulfur Batteries Using Carbon Derived from Hybrid Materials Synthesized by Twin Polymerization

Titelangaben

Choudhury, Soumyadip ; Ebert, Thomas ; Windberg, Tina ; Seifert, Andreas ; Göbel, Michael ; Simon, Frank ; Formanek, Petr ; Stamm, Manfred ; Spange, Stefan ; Ionov, Leonid:
Hierarchical Porous Carbon Cathode for Lithium–Sulfur Batteries Using Carbon Derived from Hybrid Materials Synthesized by Twin Polymerization.
In: Particle & Particle Systems Characterization. (2018) . - No.1800364.
ISSN 1521-4117
DOI: https://doi.org/10.1002/ppsc.201800364

Abstract

Abstract A new route of fabrication of cathodes for lithium–sulfur (Li–S) batteries with high cycle stability is reported. The cathodes are fabricated using porous carbon materials obtained from hybrid materials synthesized by twin polymerization on sulfonated polystyrene microparticles. The sulfonic acid groups act as room temperature catalyst for twin polymerization resulting in the formation of nanostructured phenolic resin/silica hybrid materials on the surface of sulfonated polystyrene particles. The shell formed by phenolic resin is transformed into carbon by simple pyrolysis and the polystyrene core is decomposed simultaneously at the pyrolysis temperature yielding porous carbon/silica nanocomposite hollow spheres. After silica removal, a hierarchical, highly porous carbon is obtained. Melt mixing of the carbon with sulfur is used for the fabrication of cathodes for Li–S batteries. The presence of silica on one hand imposes strength to the sphere wall during the carbonization and depolymerization of polystyrene, and on the other hand generates microporous carbon material for lithium–sulfur batteries. The nanostructured hybrid cathode allows very high capacity of 800–1000 mAh gsulfur −1 and remarkable reversible cycling stability and rate capability over 200 cycles at 0.1C rate and over 440 cycles at 1C rate for Li–S batteries.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Keywords: cathode; lithium–sulfur batteries; nanostructured hybrid materials; porous carbon; twin polymerization
Institutionen der Universität: Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation
Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation > Professur Biofabrikation - Univ.-Prof. Dr. Leonid Ionov
Fakultäten
Fakultäten > Fakultät für Ingenieurwissenschaften
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 05 Nov 2018 07:51
Letzte Änderung: 05 Nov 2018 07:51
URI: https://eref.uni-bayreuth.de/id/eprint/46228