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Unlocking the Processability and Recyclability of Biobased Poly(limonene carbonate)

Titelangaben

Neumann, Simon ; Leitner, Lisa-Cathrin ; Schmalz, Holger ; Agarwal, Seema ; Greiner, Andreas:
Unlocking the Processability and Recyclability of Biobased Poly(limonene carbonate).
In: ACS Sustainable Chemistry & Engineering. Bd. 8 (2020) Heft 16 . - S. 6442-6448.
ISSN 2168-0485
DOI: https://doi.org/10.1021/acssuschemeng.0c00895

Abstract

Poly(limonene carbonate) (PLimC) has a huge potential as a sustainable biobased polymer due to its promising property profile and the availability of the raw materials from nonedible resources, i.e., limonene from orange peel. PLimC and related terpene-based polycarbonates have not been processed from the melt state successfully due to their comparably low decomposition temperatures. Indeed, melt-processed PLimC samples are brittle and colorized. To change the paradigm, we have investigated compounds of PLimC with biobased ethyl oleate (EtOL). The glass transition temperature (Tg) and melt viscosity of these compounds can be readily controlled by the EtOL content. The melt-processed PLimC/EtOL compounds showed improved mechanical properties without significant loss in optical properties as compared to neat PLimC. Interestingly, the PLimC/EtOL compounds could be melt-processed a second time without significant loss of mechanical and optical properties, which could mark an important step toward recyclability.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Keywords: biobased; poly(limonene carbonate); fatty acid; additive; processing; recycling
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II > Lehrstuhl Makromolekulare Chemie II - Univ.-Prof. Dr. Andreas Greiner
Fakultäten
Titel an der UBT entstanden: Ja
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 28 Apr 2020 06:49
Letzte Änderung: 28 Apr 2020 06:49
URI: https://eref.uni-bayreuth.de/id/eprint/55041