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Alkylation of isobutane with 2-butene using ionic liquids as catalyst

Title data

Bui, Thi Le Thuy ; Korth, Wolfgang ; Aschauer, Stephan Josef ; Jess, Andreas:
Alkylation of isobutane with 2-butene using ionic liquids as catalyst.
In: Green Chemistry. Vol. 11 (2009) Issue 12 . - pp. 1961-1967.
ISSN 1463-9262
DOI: https://doi.org/10.1039/B913872B

Official URL: Volltext

Abstract in another language

Alkylation of isobutane with 2-butene was performed in a batch reactor using the ionic liquid 1-n-octyl-3-methylimidazolium bromide aluminium chloride ([OMIM]Br-AlCl) pure, and in a mixture with compounds containing SOH-groups. The acidity of the ionic liquid (IL) was modified by the addition of acid cation exchange resins (dry or with a small amount of water), or by the addition of a second IL ([(HOSBu)MIM]HSO). A high content of the desired trimethylpentanes (up to 64%) and thus a high research octane number (RON up to 96) of the alkylate was obtained. The reusability of the IL systems was studied and compared with a catalyst commercially used at present (HSO).

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Chemical Engineering
Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess
Faculties
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 600 Technology
600 Technology, medicine, applied sciences > 620 Engineering
600 Technology, medicine, applied sciences > 660 Chemical engineering
Date Deposited: 02 Feb 2015 08:33
Last Modified: 04 Feb 2015 09:53
URI: https://eref.uni-bayreuth.de/id/eprint/6132