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Activation of hydrogen peroxide by the nitrate anion in micellar media

Title data

Schmidt, Fabian ; Zehner, Bastian ; Kaposi, Marlene ; Drees, Markus ; Mink, János ; Korth, Wolfgang ; Jess, Andreas ; Cokoja, Mirza:
Activation of hydrogen peroxide by the nitrate anion in micellar media.
In: Green Chemistry. Vol. 23 (2021) Issue 5 . - pp. 1965-1971.
ISSN 1463-9262
DOI: https://doi.org/10.1039/D0GC03497E

Official URL: Volltext

Abstract in another language

We present the activation of hydrogen peroxide by micellar imidazolium nitrates via H-bond formation in water, as shown by vibrational spectroscopy and supported by DFT calculations. Mechanistic insight into the interactions of the surfactant cation, the nitrate anion and H2O2 is given. The micelles solubilise and epoxidise cyclooctene in the aqueous phase.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: Technical University of Munich, Faculty of Chemistry and Catalysis Research Center, München
Hungarian Academy of Science, Institute of Material and Environmental Chemistry, Budapest
Institutions of the University: Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Chair Chemical Engineering
Faculties > Faculty of Engineering Science > Chair Chemical Engineering > Chair Chemical Engineering - Univ.-Prof. Dr.-Ing. Andreas Jess
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
600 Technology, medicine, applied sciences > 600 Technology
600 Technology, medicine, applied sciences > 620 Engineering
600 Technology, medicine, applied sciences > 660 Chemical engineering
Date Deposited: 25 Jun 2021 09:00
Last Modified: 25 Jun 2021 09:00
URI: https://eref.uni-bayreuth.de/id/eprint/66178