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Kokesch-Himmelreich, Julia ; Wittek, Oliver ; Race, Alan M. ; Rakete, Sophie ; Schlicht, Clauc ; Busch, Ulrich ; Römpp, Andreas:
MALDI mass spectrometry imaging of fresh and processed food : constituents, ingredients, contaminants and additives.
Preprint from bioRxiv
,
2021
DOI: https://doi.org/10.1101/2021.12.23.473956
Abstract
Mass Spectrometry imaging (MS imaging) provides spatial information for a wide range of compound classes in different sample matrices. We used MS imaging to investigate the distribution of components in fresh and processed food, including meat, dairy and bakery products. The MS imaging workflow was optimized to cater to the specific properties and challenges of the individual samples. We successfully detected highly nonpolar and polar constituents such as beta-carotene and anthocyanins, respectively. For the first time, the distribution of a contaminant and a food additive was visualized in processed food. We detected acrylamide in German gingerbread and investigated the penetration of the preservative natamycin into cheese. For this purpose, a new data analysis tool was developed to study the penetration of analytes from uneven surfaces. Our results show that MS imaging has great potential in food analysis to provide relevant information about components’ distributions, particularly those underlying official regulations.
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