Titlebar

Export bibliographic data
Literature by the same author
plus on the publication server
plus at Google Scholar

 

CO₂ and SO₂ activation by a Cr--Cr quintuple bond

Title data

Noor, Awal ; Qayyum, Sadaf ; Bauer, Tobias ; Schwarz, Stefan ; Weber, Birgit ; Kempe, Rhett:
CO₂ and SO₂ activation by a Cr--Cr quintuple bond.
In: Chemical Communications. Vol. 50 (2014) Issue 86 . - pp. 13127-13130.
ISSN 1364-548X
DOI: https://doi.org/10.1039/c4cc05071a

Abstract in another language

A quintuply bonded dichromium complex stabilized by aminopyridinato ligands activates CO2 and SO2 by reducing the (formal) bond order of the metal-metal bonds. Oxygen abstraction is observed during CO2 activation. SO2 activation proceeds via formation of a unique dithionite complex/coordination. Furthermore, N2O activation was investigated and the formation of a tetrameric Cr-oxo complex was observed.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry II > Chair Anorganic Chemistry II - Univ.-Prof. Dr. Rhett Kempe
Result of work at the UBT: Yes
DDC Subjects: 500 Science
500 Science > 500 Natural sciences
500 Science > 540 Chemistry
Date Deposited: 10 Mar 2015 09:44
Last Modified: 10 Mar 2015 09:52
URI: https://eref.uni-bayreuth.de/id/eprint/7409