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Clay-Based Nanocomposite Coating for Flexible Optoelectronics Applying Commercial Polymers

Title data

Kunz, Daniel A. ; Schmid, Jasmin ; Feicht, Patrick ; Erath, Johann ; Fery, Andreas ; Breu, Josef:
Clay-Based Nanocomposite Coating for Flexible Optoelectronics Applying Commercial Polymers.
In: ACS Nano. Vol. 7 (2 April 2013) Issue 5 . - pp. 4275-4280.
ISSN 1936-086X
DOI: https://doi.org/10.1021/nn400713e

Abstract in another language

Transparency, flexibility, and especially ultralow oxygen (OTR) and water vapor (WVTR) transmission rates are the key issues to be addressed for packaging of flexible organic photovoltaics and organic light-emitting diodes. Concomitant optimization of all essential features is still a big challenge. Here we present a thin (1.5 μm), highly transparent, and at the same time flexible nanocomposite coating with an exceptionally low OTR and WVTR (1.0 × 10–2 cm3 m–2 day–1 bar–1 and <0.05 g m–2 day–1 at 50% RH, respectively). A commercially available polyurethane (Desmodur N 3600 and Desmophen 670 BA, Bayer MaterialScience AG) was filled with a delaminated synthetic layered silicate exhibiting huge aspect ratios of about 25 000. Functional films were prepared by simple doctor-blading a suspension of the matrix and the organophilized clay. This preparation procedure is technically benign, is easy to scale up, and may readily be applied for encapsulation of sensitive flexible electronics.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: OLED; OPV; oxygen barrier; water vapor barrier; nanocomposite; coating; layered silicate
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Physical Chemistry II
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP B 3
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP B 8
Graduate Schools > Elite Network Bavaria
Graduate Schools > Elite Network Bavaria > Struktur, Reaktivität und Eigenschaften Oxidischer Materialien
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Research Institutions
Research Institutions > Collaborative Research Centers, Research Unit
Graduate Schools
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 20 Mar 2018 13:39
Last Modified: 20 Mar 2018 13:39
URI: https://eref.uni-bayreuth.de/id/eprint/9280