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Synthesis and reversible hydration behavior of the thiosulfate intercalated layered double hydroxide of Zn and Al

Title data

Radha, S. ; Milius, Wolfgang ; Breu, Josef ; Kamath, Vishnu:
Synthesis and reversible hydration behavior of the thiosulfate intercalated layered double hydroxide of Zn and Al.
In: Journal of Solid State Chemistry. Vol. 204 (13 August 2013) . - pp. 362-366.
ISSN 0022-4596
DOI: https://doi.org/10.1016/j.jssc.2013.06.010

Abstract in another language

The thiosulfate-intercalated layered double hydroxide of Zn and Al undergoes reversible hydration with a variation in the relative humidity of the ambient. The hydrated and dehydrated phases, which represent the end members of the hydration cycle, both adopt the structure of the 3R1 polytype. In the intermediate range of relative humidity values (40–60%), the hydrated and dehydrated phases coexist. The end members of the hydration cycle adopt the structure of the same polytype, and vary only in their basal spacings. This points to the possibility that all the intermediate phases have a kinetic origin.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Layered double hydroxides; Thiosulfate ion; Hydration–dehydration; Interstratification
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie
Research Institutions > Collaborative Research Centers, Research Unit > SFB 840 Von partikulären Nanosystemen zur Mesotechnologie > SFB 840 - TP B 3
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Research Institutions
Research Institutions > Collaborative Research Centers, Research Unit
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 21 Mar 2018 09:51
Last Modified: 21 Mar 2018 09:51
URI: https://eref.uni-bayreuth.de/id/eprint/9361