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Microwave-assisted free radical polymerizations and copolymerizations of styrene and methyl methacrylate

Title data

Stange, Heiner ; Ishaque, Michael ; Nießner, Norbert ; Pepers, Michel ; Greiner, Andreas:
Microwave-assisted free radical polymerizations and copolymerizations of styrene and methyl methacrylate.
In: Macromolecular Rapid Communications. Vol. 27 (January 2006) Issue 2 . - pp. 156-161.
ISSN 1521-3927
DOI: https://doi.org/10.1002/marc.200500640

Official URL: Volltext

Abstract in another language

Radical homopolymerizations and copolymerizations of styrene were performed in toluene and N,N-dimethylformamide (DMF) as solvents using different initiators with and without microwave irradiation. Only the homopolyrnerization of styrene under microwave irradiation in DMF with DtBP showed significantly enhanced styrene conversion whereas other initiators resulted in no or only slight increase of styrene conversion under microwave irradiation. In any case. DMF was required to gain in styrene conversion under microwave irradiation. Significantly higher monomer conversions were observed under otherwise comparable conditions in the copolymerization of styrene and methyl methacrylate (MMA) in DMF Microwave-induced selectivity of monomers was not observed in copolymerizations.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: copolymerization; microwave; radical polymerization
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 07 Apr 2015 12:38
Last Modified: 04 Oct 2018 11:08
URI: https://eref.uni-bayreuth.de/id/eprint/9693