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Herling, Markus M. ; Kalo, Hussein ; Seibt, Sebastian ; Schobert, Rainer ; Breu, Josef:
Tailoring the Pore Sizes of Microporous Pillared Interlayered Clays through Layer Charge Reduction.
In: Langmuir.
Bd. 28
(2012)
Heft 41
.
- S. 14713-14719.
ISSN 1520-5827
DOI: https://doi.org/10.1021/la303573e
Abstract
A F-rich potassium hectorite, [K0.48(2)]inter[Mg2.54(8)Li0.43]oct[Si4]tetO10F2, with a layer charge of x = 0.48 per formula unit (pfu) was synthesized by high temperature melt synthesis. After Mg-exchange, the layer charge could be reduced significantly post synthesis by annealing (250 °C) as confirmed by alkylammonium exchange and cation exchange capacity. By pillaring this new low charge material with Me2DABCO2+ (N,N-dimethyl-1,1-diazabicyclo [2.2.2]octane dication) and Rh(bpy)33+ (rhodium-tris-2,2′-bipyridin trication), we observed a remarkable increase in micropore volume and pore diameter by Ar/Ar(l) physisorption measurements. This method allows the tailoring of pore sizes of pillared clays by reducing the layer charge and consequently the pillar density.