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1,3‐Bis(trimethylsilyl)‐1,3,2‐diazaphospha‐[3]ferrocenophanes

Title data

Wrackmeyer, Bernd ; Klimkina, Elena V. ; Milius, Wolfgang:
1,3‐Bis(trimethylsilyl)‐1,3,2‐diazaphospha‐[3]ferrocenophanes.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 636 (April 2010) Issue 5 . - pp. 784-794.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200900494

Abstract in another language

The 2-tert-butyl, 2-phenoxy, and 2-diethylamino derivatives of 1,3-bis(trimethylsilyl)-1,3,2-diazaphospha-[3]ferrocenophane were prepared, and the molecular structure of the latter was determined by X-ray diffraction. The phosphines could be oxidized by their slow reactions with sulfur or selenium, and the molecular structures of three sulfides and one selenide were determined. In contrast, the synthesis of oxides was less straightforward. All new compounds were characterized in solution by multinuclear magnetic resonance methods (1D and 2D 1H, 13C, 15N, 29Si, 31P, and 77Se NMR spectroscopy).

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Ferrocenes; Ferrocenophanes; Aminophosphines; NMR spectroscopy; X-ray diffraction
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 22 Mar 2018 14:49
Last Modified: 22 Mar 2018 14:49
URI: https://eref.uni-bayreuth.de/id/eprint/9919