bei Google ScholarTitelangaben
Agarwal, Seema ; Karl, Marc ; Anfang, S. ; Dehnicke, Kurt ; Greiner, Andreas:
Synthesis and Characterisation of Homopolymers and Copolymers Based on e-Caprolactone and d -Valerolactone Using Organolanthanides.
In: Abstracts of Papers of the American Chemical Society.
Bd. 216
(1998)
Heft 3
.
- U9.
ISSN 0065-7727
Abstract
The palladium-catalyzed crosscoupling reaction of boronic acids and benzyl bromides can be used successfully for the preparation of benzyls in high yield. This C-C coupling reaction was optimized for the synthesis of polybenzyls by model reactions. Different reaction channels were observed here with meta- and para-bis(bromomethyl)benzenes. The main product with 1,3-bis(chloromethyl)benzene was the corresponding 1,3-dibenzylbenzene, but the main product with 1,4-bis(chloromethyl)benzene was the corresponding biaryl resulting from homocoupling of aromatic boronic acid. 1.3-Linked polybenzyls were synthesized based on the results of the model reactions. M̄n's of 2 380 corresponding to a DP of 26 were found based on GPC. No structural defects were detected within the limits of detection.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II > Lehrstuhl Makromolekulare Chemie II - Univ.-Prof. Dr. Andreas Greiner Fakultäten Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Makromolekulare Chemie II |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 16 Apr 2015 06:20 |
| Letzte Änderung: | 24 Feb 2022 13:30 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/10240 |