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Model reactions for the synthesis of poly(1,4-phenylenevinylene). The palladium-catalyzed arylation of ethylene with halogenated arenes or benzoyl chlorides

Title data

Brenda, Martin ; Greiner, Andreas ; Heitz, Walter:
Model reactions for the synthesis of poly(1,4-phenylenevinylene). The palladium-catalyzed arylation of ethylene with halogenated arenes or benzoyl chlorides.
In: Die Makromolekulare Chemie. Vol. 191 (May 1990) Issue 5 . - pp. 1083-1100.
ISSN 0025-116X
DOI: https://doi.org/10.1002/macp.1990.021910511

Official URL: Volltext

Abstract in another language

Poly(1,4-phenylenevinylene) was obtained by reacting dibromoarenes with ethylene in a palladium-catalyzed reaction. Defects of the polymer structure were elucidated by model reactions. Side reactions in the reaction of halogenated arenes and ethylene or styrene, catalyzed by Pd, could be minimized by low catalyst concentrations and low reaction temperatures. The Pdcatalyzed reaction of aroyl chlorides with ethylene or styrene was probed by model reactions.

Further data

Item Type: Article in a journal
Refereed: Yes
Additional notes: ISI:A1990EC99500012
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II > Chair Macromolecular Chemistry II - Univ.-Prof. Dr. Andreas Greiner
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Macromolecular Chemistry II
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 17 Apr 2015 08:36
Last Modified: 09 Apr 2019 08:42
URI: https://eref.uni-bayreuth.de/id/eprint/10342