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Ferrocenylaluminum-pyridine adducts, lithium tetra(ferrocenyl)alanate, and the molecular structure of tri(ferrocenyl)aluminum-pyridine

Title data

Wrackmeyer, Bernd ; Klimkina, Elena V. ; Ackermann, Tamara ; Milius, Wolfgang:
Ferrocenylaluminum-pyridine adducts, lithium tetra(ferrocenyl)alanate, and the molecular structure of tri(ferrocenyl)aluminum-pyridine.
In: Inorganica Chimica Acta. Vol. 362 (15 August 2009) Issue 11 . - pp. 3941-3948.
ISSN 0020-1693
DOI: https://doi.org/10.1016/j.ica.2009.05.019

Abstract in another language

Aluminum compounds with up to four ferrocenyl groups (Fc) linked to aluminum were prepared and characterized in solution by NMR spectroscopy (1H, 13C, 27Al NMR), and in one case, tri(ferrocenyl)aluminum-pyridine Fc3Al-py in the solid state by X-ray structural analysis. The attempts to stabilize the unsymmetrical species R2Al-Fc and RAl(Fc)2 (R = Me, Et) as the pyridine adducts were partially successful, although it proved difficult to suppress the formation of species containing Al–Cl functions completely.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 20 Mar 2018 09:53
Last Modified: 20 Mar 2018 09:53
URI: https://eref.uni-bayreuth.de/id/eprint/10448