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A Route to Microporous Materials through Oxidative Pillaring of Micas

Title data

Baumgartner, Alexander ; Sattler, Katrin ; Thun, Jürgen ; Breu, Josef:
A Route to Microporous Materials through Oxidative Pillaring of Micas.
In: Angewandte Chemie International Edition. Vol. 47 (15 February 2008) Issue 9 . - pp. 1640-1644.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.200704790

Abstract in another language

Oxidative pillaring: The intercalation of a molecular pillar (Me2DABCO2+) into synthetic Cs-tainiolite, which shows sufficient intracrystalline reactivity by an oxidative cation-exchange mechanism, yields a material with microporosity that resembles zeolites in both narrow pore size distribution and total pore volume. Owing to the high structural Fe content, this pillared clay provides a size-selective, shape-selective, and electronically conducting framework.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: intercalations; layered compounds; microporous materials; silicates
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I > Chair Anorganic Chemistry I - Univ.-Prof. Dr. Josef Breu
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry I
Result of work at the UBT: Yes
DDC Subjects: 500 Science
500 Science > 540 Chemistry
Date Deposited: 26 Mar 2018 07:19
Last Modified: 26 Mar 2018 07:19
URI: https://eref.uni-bayreuth.de/id/eprint/10460