New Amphiphilic Nanostructures Based on Block Terpolymers Made By Anionic Polymerization

Titelangaben

Schacher, Felix H. ; Reinicke, Stefan ; Walther, Andreas ; Schmalz, Holger ; Müller, Axel H. E.:
New Amphiphilic Nanostructures Based on Block Terpolymers Made By Anionic Polymerization.
In: Khosravi, Ezat (ed.): New Smart Materials via Metal Mediated Macromolecular Engineering. - Dordrecht : Springer , 2009 . - S. 167-186 . - (NATO Science for Peace and Security : Series A, Chemistry and Biology )
ISBN 978-90-481-3278-2
DOI: https://doi.org/10.1007/978-90-481-3278-2_10

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Abstract

Anionic polymerization is the method of choice to synthesize linear and miktoarm-star block copolymers with high molecular weights and very narrow molecular weight distributions. We report on the synthesis of some new block co- and terpolymers and on the self-organized nanostructures they form in the bulk and in solution. Bulk structures are used as novel stimuli-sensitive membranes, whereas solution structures are soft nanoparticles, which have either a compartmentalized core or corona: new multicompartment-core micelles, Janus nanoparticles and cylinders with multicompartment corona.