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The valence states of vanadium in the low-temperature superstructure of NaV₂O₅

Title data

van Smaalen, Sander ; Lüdecke, Jens:
The valence states of vanadium in the low-temperature superstructure of NaV₂O₅.
In: Europhysics Letters. Vol. 49 (2000) Issue 2 . - pp. 250-254.
ISSN 0295-5075
DOI: https://doi.org/10.1209/epl/i2000-00141-0

Abstract in another language

We have applied the bond-valence method to calculate the valencies of the vanadium atoms in the low-temperature superstructure of α'-NaV 2 O 5 . The modulated ladders are found to comprise V 4+ and V 5+ cations in a zigzag type of charge order. The non-modulated ladders comprise a single type of vanadium atom in the mixed-valence state V 4.5 + .

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography
Faculties
Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
Date Deposited: 01 Apr 2016 05:57
Last Modified: 01 Apr 2016 05:57
URI: https://eref.uni-bayreuth.de/id/eprint/32097