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Synthesis and Crystal Structure of Rb₆Pb₅Cl₁₆

Title data

Beck, Horst P. ; Schramm, Manfred ; Haberkorn, Robert ; Dinnebier, Robert E. ; Stephens, Peter W.:
Synthesis and Crystal Structure of Rb₆Pb₅Cl₁₆.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 624 (1998) Issue 3 . - pp. 393-398.
ISSN 1521-3749
DOI: https://doi.org/10.1002/(SICI)1521-3749(199803)624:3<393::AID-ZAAC393>3.0.CO;2-V

Official URL: Volltext

Abstract in another language

The synthesis of a hitherto unknown 6 : 5 phase in the quasi-binary system RbCl/PbCl2 and its structure determination is reported. The compound Rb6Pb5Cl16 crystallizes in the tetragonal space group P4/mbm with a large variety of different coordination polyhedra for the cations. Special feature of the structure is a statistical distribution of Rb and Pb at one of the cation sites with a ratio of 1 : 3 as defined by electroneutrality. There is no evidence for symmetry reduction by ordering.

Further data

Item Type: Article in a journal
Refereed: Yes
Keywords: Ternary halide; lone pair cation; high coordination
Institutions of the University: Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences > Chair Crystallography
Faculties
Faculties > Faculty of Mathematics, Physics und Computer Science
Faculties > Faculty of Mathematics, Physics und Computer Science > Group Material Sciences
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 530 Physics
Date Deposited: 14 Jun 2016 08:53
Last Modified: 14 Jun 2016 08:53
URI: https://eref.uni-bayreuth.de/id/eprint/32667