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Reinsch, Helge ; Pillai, Renjith S. ; Siegel, Renée ; Senker, Jürgen ; Lieb, Alexandra ; Maurin, Guillaume ; Stock, Norbert:
Structure and properties of Al-MIL-53-ADP, a breathing MOF based on the aliphatic linker molecule adipic acid.
In: Dalton Transactions.
Bd. 45
(2016)
Heft 10
.
- S. 4179-4186.
ISSN 1477-9234
DOI: https://doi.org/10.1039/C5DT03510D
Abstract
The new aluminium based metal-organic framework Al(OH)(O2C-C4H8-CO2)].H2O denoted as AlMIL- 53-ADP-lp (lp stands for large pore) was synthesised under solvothermal conditions. This solid is an analogue of the archetypical aluminium terephthalate Al-MIL-53 based on the aliphatic single-chain linker molecule adipic acid (H(2)ADP, hexanedioic acid). In contrast to its aromatic counterparts, Al-MIL-53ADP exhibits a structural breathing behaviour solely upon dehydration/rehydration. The crystal structure of the anhydrous compound denoted as Al-MIL-53-ADP-np (np stands for narrow pore) was determined by a combination of forcefield-based computations and Rietveld refinement of the powder X-ray diffraction data while the structure of the hydrated form Al-MIL-53-ADP-lp was derived computationally by a combination of force field based methods and Density Functional Theory calculations. Both structures were further supported by H-1, C-13 and Al-27 high-resolution NMR MAS 1D data coupled again with simulations. Al-MIL-53-ADP was further characterised by means of vibrational spectroscopy, elemental analysis, thermogravimetry and water vapour sorption.
Weitere Angaben
| Publikationsform: | Artikel in einer Zeitschrift |
|---|---|
| Begutachteter Beitrag: | Ja |
| Institutionen der Universität: | Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Anorganische Chemie III > Lehrstuhl Anorganische Chemie III - Univ.-Prof. Dr. Jürgen Senker Fakultäten Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Lehrstuhl Anorganische Chemie III |
| Titel an der UBT entstanden: | Nein |
| Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| Eingestellt am: | 26 Jul 2016 14:09 |
| Letzte Änderung: | 12 Jun 2019 05:55 |
| URI: | https://eref.uni-bayreuth.de/id/eprint/33649 |