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Structure and properties of Al-MIL-53-ADP, a breathing MOF based on the aliphatic linker molecule adipic acid

Title data

Reinsch, Helge ; Pillai, Renjith S. ; Siegel, Renée ; Senker, Jürgen ; Lieb, Alexandra ; Maurin, Guillaume ; Stock, Norbert:
Structure and properties of Al-MIL-53-ADP, a breathing MOF based on the aliphatic linker molecule adipic acid.
In: Dalton Transactions. Vol. 45 (2016) Issue 10 . - pp. 4179-4186.
ISSN 1477-9234
DOI: https://doi.org/10.1039/C5DT03510D

Abstract in another language

The new aluminium based metal-organic framework Al(OH)(O2C-C4H8-CO2)].H2O denoted as AlMIL- 53-ADP-lp (lp stands for large pore) was synthesised under solvothermal conditions. This solid is an analogue of the archetypical aluminium terephthalate Al-MIL-53 based on the aliphatic single-chain linker molecule adipic acid (H(2)ADP, hexanedioic acid). In contrast to its aromatic counterparts, Al-MIL-53ADP exhibits a structural breathing behaviour solely upon dehydration/rehydration. The crystal structure of the anhydrous compound denoted as Al-MIL-53-ADP-np (np stands for narrow pore) was determined by a combination of forcefield-based computations and Rietveld refinement of the powder X-ray diffraction data while the structure of the hydrated form Al-MIL-53-ADP-lp was derived computationally by a combination of force field based methods and Density Functional Theory calculations. Both structures were further supported by H-1, C-13 and Al-27 high-resolution NMR MAS 1D data coupled again with simulations. Al-MIL-53-ADP was further characterised by means of vibrational spectroscopy, elemental analysis, thermogravimetry and water vapour sorption.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry III > Chair Anorganic Chemistry III - Univ.-Prof. Dr. Jürgen Senker
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry III
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 26 Jul 2016 14:09
Last Modified: 12 Jun 2019 05:55
URI: https://eref.uni-bayreuth.de/id/eprint/33649