Titelangaben
Kudina, Olena ; Zakharchenko, Andrey ; Trotsenko, Oleksandr ; Tokarev, Alexander ; Ionov, Leonid ; Stoychev, Georgi ; Puretskiy, Nikolay ; Pryor, Scott W. ; Voronov, Andriy ; Minko, Sergiy:
Highly Efficient Phase Boundary Biocatalysis with Enzymogel Nanoparticles.
In: Angewandte Chemie International Edition.
Bd. 53
(2014)
Heft 2
.
- S. 483-487.
ISSN 1521-3773
DOI: https://doi.org/10.1002/anie.201306831
Abstract
The enzymogel nanoparticle made of a magnetic core and polymer brush shell demonstrates a novel type of remote controlled phase-boundary biocatalysis that involves remotely directed binding to and engulfing insoluble substrates, high mobility, and stability of the catalytic centers. The mobile enzymes reside in the polymer brush scaffold and shuttle between the enzymogel interior and surface of the engulfed substrate in the bioconversion process. Biocatalytic activity of the mobile enzymes is preserved in the enzymogel while the brush-like architecture favors the efficient interfacial interaction when the enzymogel spreads over the substrate and extends substantially the reaction area as compared with rigid particles.
Weitere Angaben
Publikationsform: | Artikel in einer Zeitschrift |
---|---|
Begutachteter Beitrag: | Ja |
Keywords: | bioconversion; enzymatic catalysis; nanoparticles; polymer brushes; stimuli-responsive materials |
Institutionen der Universität: | Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation > Professur Biofabrikation - Univ.-Prof. Dr. Leonid Ionov Fakultäten Fakultäten > Fakultät für Ingenieurwissenschaften Fakultäten > Fakultät für Ingenieurwissenschaften > Professur Biofabrikation |
Titel an der UBT entstanden: | Ja |
Themengebiete aus DDC: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
Eingestellt am: | 20 Jun 2017 10:02 |
Letzte Änderung: | 10 Mär 2022 10:00 |
URI: | https://eref.uni-bayreuth.de/id/eprint/37687 |