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Reversible Chemical Patterning on Stimuli-Responsive Polymer Film :  Environment-Responsive Lithography

Title data

Ionov, Leonid ; Minko, Sergiy ; Stamm, Manfred ; Gohy, Jean-François ; Jérôme, Robert ; Scholl, Andreas:
Reversible Chemical Patterning on Stimuli-Responsive Polymer Film :  Environment-Responsive Lithography.
In: Journal of the American Chemical Society. Vol. 125 (1 July 2003) Issue 27 . - pp. 8302-8306.
ISSN 1520-5126
DOI: https://doi.org/10.1021/ja035560n

Abstract in another language

We report on a novel type of chemical patterning based on thin stimuli−responsive polymer films. The basic concept is the permanent storage (writing) of a pattern, which is reversibly developed and erased upon exposure to appropriate environment, e.g., solvent, pH, and temperature. The smart surface is fabricated from the mixed brush of poly(2-vinylpyridine) and polyisoprene. The mixed brush demonstrates switching behavior upon exposure to different solvents. Cross-linking of polyisoprene via illumination through a photomask results in formation of patterns with suppressed switching. Due to the contrast in switching between illuminated and dark areas, exposure of the smart surface to different solvents causes either reversible formation or erasing of chemical contrast between the illuminated and dark areas. Thus, the pattern surface can very locally attract colloidal particles or can be wetted by water only upon exposure to the special solvent which introduces the contrast between the illuminated and dark areas. Appearance of the patterns indicates particular environment and can be used for local switching of adsorption.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Engineering Science > Professur Biofabrikation > Professur Biofabrikation - Univ.-Prof. Dr. Leonid Ionov
Faculties
Faculties > Faculty of Engineering Science
Faculties > Faculty of Engineering Science > Professur Biofabrikation
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 21 Jun 2017 11:48
Last Modified: 21 Jun 2017 11:48
URI: https://eref.uni-bayreuth.de/id/eprint/37714