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Structural Complexity in Metal–Organic Frameworks : Simultaneous Modification of Open Metal Sites and Hierarchical Porosity by Systematic Doping with Defective Linkers

Titelangaben

Fang, Zhenlan ; Dürholt, Johannes P. ; Kauer, Max ; Zhang, Wenhua ; Lochenie, Charles ; Jee, Bettina ; Albada, Bauke ; Metzler-Nolte, Nils ; Pöppl, Andreas ; Weber, Birgit ; Muhler, Martin ; Wang, Yuemin ; Schmid, Rochus ; Fischer, Roland A.:
Structural Complexity in Metal–Organic Frameworks : Simultaneous Modification of Open Metal Sites and Hierarchical Porosity by Systematic Doping with Defective Linkers.
In: Journal of the American Chemical Society. Bd. 136 (2014) Heft 27 . - S. 9627-9636.
ISSN 1520-5126
DOI: https://doi.org/10.1021/ja503218j

Abstract

A series of defect-engineered metal-organic frameworks (DEMOFs) derived from parent microporous MOFs was obtained by systematic doping with defective linkers during synthesis, leading to the simultaneous and controllable modification of coordinatively unsaturated metal sites (CUS) and introduction of functionalized mesopores. These materials were investigated via temperature-dependent adsorption/desorption of CO monitored by FTIR spectroscopy under ultra-high-vacuum conditions. Accurate structural models for the generated point defects at CUS were deduced by matching experimental data with theoretical simulation. The results reveal multivariate diversity of electronic and steric properties at CUS, demonstrating the MOF defect structure modulation at two length scales in a single step to overcome restricted active site specificity and confined coordination space at CUS. Moreover, the DEMOFs exhibit promising modified physical properties, including band gap, magnetism, and porosity, with hierarchical micro/mesopore structures correlated with the nature and the degree of defective linker incorporation into the framework.

Weitere Angaben

Publikationsform: Artikel in einer Zeitschrift
Begutachteter Beitrag: Ja
Institutionen der Universität: Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Professur Anorganische Chemie IV > Professur Anorganische Chemie IV - Univ.-Prof. Dr. Birgit Weber
Fakultäten
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie
Fakultäten > Fakultät für Biologie, Chemie und Geowissenschaften > Fachgruppe Chemie > Professur Anorganische Chemie IV
Titel an der UBT entstanden: Nein
Themengebiete aus DDC: 500 Naturwissenschaften und Mathematik > 540 Chemie
Eingestellt am: 25 Jul 2017 13:13
Letzte Änderung: 25 Jul 2017 13:13
URI: https://eref.uni-bayreuth.de/id/eprint/38810