A ladder type iron(II) coordination polymer with cooperative spin transition

Titelangaben

Bauer, Wolfgang ; Schlamp, Stephan ; Weber, Birgit:
A ladder type iron(II) coordination polymer with cooperative spin transition.
In: Chemical Communications. Bd. 48 (2012) Heft 82 . - S. 10222-10224.
ISSN 1364-548X
DOI: https://doi.org/10.1039/C2CC35109A

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Abstract

Ladder type 1D coordination polymers were synthesised with the aim to improve the spin crossover properties of the iron(ii) complexes following the concepts of crystal engineering. A wide hysteresis loop (34 K) was observed if rigid linkers were used. The first X-ray structure for a 1D iron(ii) ladder is reported.