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Synthesis of Anionic Spin Crossover Complexes with Schiff Base like Ligands

Title data

Schlamp, Stephan ; Schulten, Johanna ; Betz, Richard ; Bauch, Tobias ; Mudring, Anja Verena ; Weber, Birgit:
Synthesis of Anionic Spin Crossover Complexes with Schiff Base like Ligands.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 638 (2012) Issue 7-8 . - pp. 1093-1102.
ISSN 0044-2313
DOI: https://doi.org/10.1002/zaac.201200162

Abstract in another language

The reaction of neutral iron(II) complexes of tetradentate Schiff base like ligands with the pseudohalogenides SCN–, OCN–, and CN– as monodentate axial ligands was investigated. In solution the formation of octahedral complexes could be confirmed and it was possible to follow a spin transition by T-dependent 1H NMR spectroscopy. In the solid only pentacoordinate complexes were obtained and the X-ray structure of five monoanionic pentacoordinate iron(II) complexes and an interesting trinuclear complex are discussed.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: Yes
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 26 Jul 2017 12:06
Last Modified: 26 Jul 2017 12:06
URI: https://eref.uni-bayreuth.de/id/eprint/38826