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Crystal Structure of Iron(II) Acetate

Title data

Weber, Birgit ; Betz, Richard ; Bauer, Wolfgang ; Schlamp, Stephan:
Crystal Structure of Iron(II) Acetate.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 637 (2011) Issue 1 . - pp. 102-107.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.201000274

Abstract in another language

In this paper the X-ray structure and magnetic properties of iron(II) acetate – starting material for the synthesis of a wide range of iron complexes – are presented. The compound crystallises in the space group Pbcn and was identified as 2D coordination polymer consisting of iron atoms and acetate moieties with all the iron atoms hexacoordinate and different coordination modes for the acetate moieties. Additional hydrogen bond contacts lead to a porous coordination polymer with 1D channels in the size of mesopores. Temperature dependent magnetic measurements confirm that the complex is a high-spin compound in the entire temperature range investigated with a room temperature magnetic moment of 5.4 μB. Field-dependent magnetisation measurements reveal a slightly sigmoidal curve progression typical for metamagnetism.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 27 Jul 2017 12:11
Last Modified: 27 Jul 2017 12:11
URI: https://eref.uni-bayreuth.de/id/eprint/38837