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A Promising New Schiff Base-like Ligand for the Synthesis of Octahedral Iron(II) Spin Crossover Complexes

Title data

Bauer, Wolfgang ; Ossiander, Tanja ; Weber, Birgit:
A Promising New Schiff Base-like Ligand for the Synthesis of Octahedral Iron(II) Spin Crossover Complexes.
In: Zeitschrift für Naturforschung B. Vol. 65b (2010) . - pp. 323-328.
ISSN 1865-7117

Official URL: Volltext

Abstract in another language

A new tetradentate Schiff base-like ligand H2L (1) ((E,E)-dimethyl-2,2-[1,2-phenylenebis(aminomethylidyne)]bis[3-oxobutanoate]) was synthesised and structurally characterised. Its reaction with iron(II) acetate leads to the formation of the octahedral N2O4-coordinated complex [FeL(MeOH)2](2). The complex is a pure high-spin (HS) compound as is evident from magnetic measurements and X-ray crystallography.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 27 Jul 2017 12:18
Last Modified: 27 Jul 2017 12:18
URI: https://eref.uni-bayreuth.de/id/eprint/38838