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Synthesis and Characterisation of a New Schiff-Base-like Ligand and its Iron(II) Complexes

Title data

Weber, Birgit ; Obel, Jaroslava:
Synthesis and Characterisation of a New Schiff-Base-like Ligand and its Iron(II) Complexes.
In: Zeitschrift für anorganische und allgemeine Chemie. Vol. 635 (2009) Issue 15 . - pp. 2474-2479.
ISSN 1521-3749
DOI: https://doi.org/10.1002/zaac.200900241

Abstract in another language

The reaction of iron(II) acetate with the tetradentate Schiff base like ligand H2L [(E,E)-[{diethyl 2,2’-[4,5-dihydroxy-1,2-phenylenebis(iminomethylidyne)]bis3-oxobutanato}]) leads to the formation of the octahedral N2O4 coordinated complex [FeL(MeOH)2]·MeOH (1). Conversion of 1 with N-methylimidazole (N-meim) leads to the N4O2 coordinated complex [FeL(N-meim)2]·MeOH (2). Both complexes are pure HS compounds that were characterised using magnetic measurements and X-ray crystallography. A special attention was given to the role of the two hydroxyl groups at the phenyl ring on the formation of a hydrogen bond network and the influence of this network on the magnetic properties.

Further data

Item Type: Article in a journal
Refereed: Yes
Institutions of the University: Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV > Chair Anorganic Chemistry IV - Univ.-Prof. Dr. Birgit Weber
Faculties
Faculties > Faculty of Biology, Chemistry and Earth Sciences
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry
Faculties > Faculty of Biology, Chemistry and Earth Sciences > Department of Chemistry > Chair Anorganic Chemistry IV
Result of work at the UBT: No
DDC Subjects: 500 Science > 540 Chemistry
Date Deposited: 27 Jul 2017 12:52
Last Modified: 27 Jul 2017 12:52
URI: https://eref.uni-bayreuth.de/id/eprint/38847